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Jose Mourinho's side are into the next round of the Europa League, after beating Ludogorets 3-1 on Thursday evening.
Having finished second in the group behind Real Betis, the Giallorossi will now have to face one of the sides that finished third in their Champons League groups.
The draw for the play-off round takes place on Monday in Nyon. It is scheduled to begin at 13:00 CET.
The seven sides Roma could be drawn against are: Ajax, Bayer Leverkusen, Barcelona, RB Salzburg, Shakhtar Donetsk, Sevilla and Sporting Clube de Portugal.
Roma cannot face the eighth side to drop down from the Champions League, Juventus, due to UEFA's rule about clubs from the same country facing each other in the first knockout round.
The eventual matches will take place on February 16 and February 23.
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