Roma's squad, which includes World Cup winners Bruno Conti, Cafu, Aldair and Simone Perrotta, arrived in Madrid on Saturday afternoon - and were then invited to a restaurant at the Santiago Bernabeu later in the evening.
Butragueno, who attended the meal, discussed the game before showing the players around the stadium - including the club's recently-expanded collection of 12 European Cups.
"It is our honour to have you join us for this important cause," Butragueno said.
All proceeds from the charity match are being donated to various projects in Africa.
Click here to see the Roma squad for Sunday's game.
See more photos from the evening in the gallery below.
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