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The game, which takes place at the Stadio Citta di Arezzo, gets underway at 19:30 local time.
The game is being broadcast live on Roma TV in Italy – and also to fans around the world on the club’s Facebook, Twitter and YouTube accounts.
Paulo Fonseca has named a strong squad for the game, with 21 first-team players available.
Arezzo finished fourth in Group A of Serie C last season, eventually losing out in the promotion play-off semi-finals.
The game will be Roma’s fifth official encounter of pre-season, after wins against Perugia and Lille and draws with Athletic Club and Real Madrid.
The side, coached by Daniele Di Donato, begin their 2019-20 campaign on August 25 against Lecco.
Roma also get their season underway that day – hosting Genoa at the Stadio Olimpico.
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