The Giallorossi will travel to the Stadio Citta di Arezzo for the match against the Serie C side, with kick-off scheduled for 19:30 local time.
Ticket information for the game will be released in due course.
The game will be Roma’s fifth official encounter of pre-season, after wins against Perugia and Lille and draws with Athletic Club and Real Madrid.
Arezzo finished fourth in Group A of Serie C last season, eventually losing out in the promotion play-off semi-finals.
The side, coached by Daniele Di Donato, begin their 2019-20 campaign on August 25 against Lecco.
Roma also get their season underway that day – hosting Genoa at the Stadio Olimpico.
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