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The Giallorossi eventually went down to a heavy 4-0 defeat at the Stadio San Paolo, as Lorenzo Insigne, Fabian Ruiz, Dries Mertens and Matteo Politano got on the scoresheet.
The Giallorossi are back in action in midweek - they host Young Boys in the Europa League on Thursday night.
Paulo Fonseca's side have already qualified for the knockout stages of the competition.
NAPOLI 4-0 ROMA
GOALSCORERS: Insigne (31'), Fabian Ruiz (64'), Mertens (81'), Politano (86')
NAPOLI (4-2-3-1): Meret; Di Lorenzo, Manolas, Koulibaly, Mario Rui; Fabian Ruiz, Demme (Lobotka); Lozano (Politano), Zielinski (Elmas), Insigne; Mertens (Petagna)
Unused subs: Contini, Ospina, Malcuit, Llorente, Maksimovic, Ghoulam
ROMA (3-4-2-1): Mirante; Mancini (Juan Jesus), Cristante, Ibanez; Karsdorp, Veretout (Villar), Pellegrini (Borja Mayoral), Spinazzola; Mkhitaryan, Pedro; Dzeko (Perez)
Unused subs: Farelli, Pau Lopez, Peres, Diawara, Feratovic, Providence, Calafiori
Imperium Partners
Centurion Partners
