The midfielder, captain on the night, led from the front as the Giallorossi overcame a 4-1 first leg deficit to beat the Spanish champions 3-0 on the night - and progress from the tie on away goals.
De Rossi scored the crucial second goal of the night, converting a penalty nervelessly to set up the dramatic scenes that surrounded Kostas Manolas's winner.
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De Rossi's performance earned just over 50% of the fan vote on Twitter - with Edin Dzeko's talismanic two-goal display in last season's 4-2 win at Napoli coming in second.
Congratulations Daniele!
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