The duo, who were part of Antonio Conte's squad for this summer's European Championship, will join up with the Azzurri for the games against France and Israel.
However, there is no place on this occasion for Stephan El Shaarawy - the third Giallorossi player to represent the Azzurri in France.
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De Rossi and Florenzi will join up with the national team on Monday, following the conclusion of Roma's Serie A game against Cagliari.
Ventura has picked 15 of the 23 players that Conte took to the Euros - but has also included some new faces like teenage goalkeeper Gianluigi Donnarumma and forward Andrea Belotti.
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